SLIIT International Conference On Engineering and Technology Vol. 03 [SICET] 2024
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Publication Embargo Development of DSSC Counter Electrode Using PEDOT: PSS/GO Nanocomposite(SLIIT, Faculty of Engineering, 2024-10) Ravindran, N. S; Wijayarathne, W. M. K. B. N; Chandrika, R. P.; Medagedara, A. D. T.; Kumara, G. R. A; Bandara, T. M. W. J.Dye-sensitized solar cells (DSSCs) have garnered considerable research interest owing to their ability to achieve high photo-to-electric energy conversion efficiencies at a relatively low production cost. While platinum has been recognized for its exceptional electrocatalytic performance and efficiency as a counter electrode in DSSCs, its higher cost and vulnerability to corrosion have prompted the exploration of alternative materials to replace Pt in this role. DSSCs have demonstrated noteworthy photovoltaic performances by employing a range of candidate materials, including conducting polymers, carbon materials, and nanocomposites of conducting polymers and carbon materials, as counter electrodes. The motivation to form composites or hybrids with nanomaterials stems from the aim to improve the overall photovoltaic efficiency in DSSCs. The main objective of this study was to fabricate a DSSC utilizing a counter electrode comprised of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate and graphene oxide (PEDOT: PSS/GO). The fabrication of the counter electrode involved depositing the PEDOT: PSS/GO nanocomposite onto a graphite sheet using drop casting. The GO, which was synthesized through a modified version of Hummer’s method, underwent characterization via Raman spectroscopy and XRD analysis to ensure a successful synthesis process. The surface morphology and the Raman spectra of coated nanocomposites indicated the good dispersion of GO and the strong interaction between GO and the PSS chain, respectively. In the fabrication process of the DSSC, a gel polymer electrolyte was incorporated between a five-layer TiO2-based photoanode and the PEDOT: PSS/GO-based counter electrode. Photovoltaic performances of DSSCs were evaluated under simulated solar irradiance of 1000 W m-2. They were able to achieve a power conversion efficiency of 2.7%, Voc of 0.73 mV, Jsc of 5.21 mA cm-2, and a fill factor of 0.71.Publication Embargo Efficiency Enhanced by Chelation of Al3+ Metal Ions with Erythrina Fusca Flower Dye Harnessing Bathochromic Shift(SLIIT, Faculty of Engineering, 2024-10) Mannawadu, M.W.M.K; Perera, V.P.S.Utilization of natural dyes in dye-sensitized solar cells (DSSCs) presents a sustainable approach towards enhancing photovoltaic efficiency. This study explores the bathochromic shift exhibited by Erythrina fusca (Erabodu) flower dye upon chelation with Al3+ ions, offering an innovative strategy for improving DSSC performance. 20g of chopped flower petals was boiled with 50ml of ethanol until flower petals become pale in colour in the dye extraction process. After that, 0.1 M, AlCl3 solution was added dropwise to 2ml of dye solution until the colour changed to purple. The pH value of Erabadu bare dye was recorded as 5.47 and with the Al3+ ion addition it was changed to 4.49. Through spectroscopic analysis and electrochemical characterization, the chelation mechanism and its impact on dye absorption spectra and electron transfer dynamics was elucidated. The Dye was coated on a thin film of TiO2 nanoparticles deposited on fluorine-doped tin oxide (FTO) glass plates. FTO glass which coated with platinum was used as the counter electrode and iodin/triiodide (I2 / I3 -) was used as the electrolyte. Solar cell was tested with a light source with an intensity of 100 mW/cm2. Al3+ ion chelated Erabadu dye exhibited higher efficiencies than bare dye which was 1.627%. The open circuit voltage (Voc) of this cell was 470mV, short circuit current density (Jsc) was 4.00 mA/cm2 and the fill factor of DSSC’s was 0.553. The Incident Photon to Current Conversion Efficiency (IPCE) of the cell further revealed the action spectrum was broadened between 300 nm – 500 nm enhancing the efficiency. Our findings unveil the potential of Al3+ ion chelated Erythrina fusca dye as a promising sensitizer for DSSCs, paving the way for eco-friendly and efficient solar energy conversion.