Faculty of Engineering
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Publication Embargo Fatigue properties of catalyst coated membranes for fuel cells: Ex-situ measurements supported by numerical simulations(Pergamon, 2016-06-08) Khorasany, R. M. H; Singh, Y; Alavijeh, A. S; Kjeang, E; Wang, G. G; Rajapakse, R. K. N. DThe interactions between catalyst layers and membrane are known to have significant impact on the mechanical properties of the composite catalyst coated membrane (CCM) materials used in fuel cells. The mechanical fatigue durability of such composite CCM materials is investigated herein, and compared to the characteristics of pure membranes. Ex-situ uniaxial cyclic tension tests are conducted under controlled environmental conditions to measure the fatigue lifetime, defined by the number of stress cycles that the specimen can withstand before mechanical failure. The sensitivity of the CCM fatigue lifetime to the applied stress is determined to be higher than that of the pure membrane, and varies significantly with environmental conditions. The experimental results are then utilized to develop a finite element based CCM fatigue model featuring an elastic–plastic constitutive relation with strain hardening. Upon validation, the model is used to simulate the fatigue durability of the CCM under cyclic variations in temperature and relative humidity, which is critical for fuel cells but cannot be effectively measured ex-situ. When combined, the experimental and numerical methods demonstrated in this work provide a novel, convenient approach to determine the CCM fatigue durability under various hygrothermal loading conditions of relevance for fuel cell design and operation.Publication Embargo Decay in Mechanical Properties of Catalyst Coated Membranes Subjected to Combined Chemical and Mechanical Membrane Degradation(Wily, 2014-11-28) Rajapakse, R. K. N. D; Wang, G. G; Lauritzen, M; Kjeang, E; Lim, C; Ghataurah, J; Khorasany, R. M. H; Goulet, M. A; Alavijeh, A. SThe mechanical stability of catalyst coated membranes (CCMs) is an important factor for the overall durability and lifetime of polymer electrolyte fuel cells. In this article, the evolution of the mechanical properties of degraded CCMs is comprehensively assessed. A combined chemical and mechanical accelerated stress test (AST) was applied to simulate field operation and rapidly generate partially degraded CCM samples for tensile and expansion experiments under both room and fuel cell conditions. The tensile results indicated significant reductions in ultimate tensile strength, toughness, and fracture strain as a function of AST cycles, accompanied by a mild increase in elastic modulus. The increased brittleness and reduced fracture toughness of the CCM, caused primarily by chemical membrane degradation, is expected to play an important role in the ultimate failure of the fuel cell. The expansion tests revealed a linear decay in hygrothermal expansion, similar in magnitude to the loss of mechanical strength. The decline in CCM sensitivity to environmental changes leads to non-uniform swelling and contraction that may exacerbate local degradation. Interestingly, the hygrothermal expansion in the late stages of degradation coincided with the fracture strain, which correlates to in situ development of fractures in chemically weakened membranes.Publication Open Access Accelerated membrane durability testing of heavy duty fuel cells(IOP Publishing, 2014-11-19) Macauley, N; Alavijeh, A. S; Watson, M; Kolodziej, J; Lauritzen, M; Knights, S; Wang, G; Kjeang, ERegular durability testing of heavy duty fuel cell systems for transit bus application requires several thousand hours of operation, which is costly and time consuming. Alternatively, accelerated durability tests are able to generate failure modes observed in field operation in a compressed time period, by applying enhanced levels of stress. The objective of the present work is to design and validate an accelerated membrane durability test (AMDT) for heavy duty fuel cells under bus related conditions. The proposed AMDT generates bus relevant membrane failure modes in a few hundred hours, which is more than an order of magnitude faster than for regular duty cycle testing. Elevated voltage, temperature, and oxidant levels are used to accelerate membrane chemical stress, while relative humidity (RH) cycling is used to induce mechanical stress. RH cycling is found to significantly reduce membrane life-time compared to constant RH conditions. The role of a platinum band in the membrane is investigated and membranes with Pt bands demonstrate a considerable life-time extension under AMDT conditions, with minimal membrane degradation. Overall, this research serves to establish a benchmark AMDT that can rapidly and reliably evaluate membrane stability under simulated heavy duty fuel cell conditions.Publication Embargo Mechanical degradation of fuel cell membranes under fatigue fracture tests(Elsevier, 2015-01-01) Khorasany, Ramin M.H; Alavijeh, A. S; Kjeang, E.; Wang, G.G.; Rajapakse, R. K. N. DThe effects of cyclic stresses on the fatigue and mechanical stability of perfluorosulfonic acid (PFSA) membranes are experimentally investigated under standard fuel cell conditions. The experiments are conducted ex-situ by subjecting membrane specimens to cyclic uniaxial tension at controlled temperature and relative humidity. The fatigue lifetime is measured in terms of the number of cycles until ultimate fracture. The results indicate that the membrane fatigue lifetime is a strong function of the applied stress, temperature, and relative humidity. The fatigue life increases exponentially with reduced stresses in all cases. The effect of temperature is found to be more significant than that of humidity, with reduced fatigue life at high temperatures. The maximum membrane strain at fracture is determined to decrease exponentially with increasing membrane lifetime. At a given fatigue life, a membrane exposed to fuel cell conditions is shown to accommodate more plastic strain before fracture than one exposed to room conditions. Overall, the proposed ex-situ membrane fatigue experiment can be utilized to benchmark the fatigue lifetime of new materials in a fraction of the time and cost associated with conventional in-situ accelerated stress testing methods.