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    PublicationOpen Access
    Detecting a decline in serial homicide: Have we banished the devil from the details?
    (Cogent, 2019-01-01) Yaksic, E; Allely, C; De Silva, R; Smith-Inglis, M; Konikoff, D; Konikoff, K; Gordon, D; Denisov, E; Keatley, D. A
    The current research provides perspective regarding the true prevalence of serial murderers in modern society and addresses the conflict between the evidenced decline in serial homicide and the viewpoint that the phenomenon is increasing. The likelihood that serial murderers are responsible for most unresolved homicides and missing persons is examined in the context of a declining prevalence. A mixed methods approach was used, consisting of a review of a sample of unresolved homicides, a comparative analysis of the frequency of known serial homicide series and unresolved serial homicide series, and semi-structured interviews of experts. In failing to become serial killers, aspiring and probable serial killers and spree killers have impacted the rate of serial murder by not reaching their potential. The past decade contained almost half the cases (13%) that existed at the 1980s peak of serial homicide (27%). Only 282 (1.3%) strangled females made up the 22,444 unresolved homicides reviewed. Most expert respondents thought it unreasonable that any meaningful proportion of missing persons cases are victims of serial homicide. Technology, shifts in offending behavior, proactive law enforcement action, and vigilance of society have transformed serial killing and aids in viewing offenders as people impacted by societal shifts and cultural norms. The absence of narrative details inhibited some aspects of the review. An exhaustive list
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    PublicationEmbargo
    Catalytic graphitization in nanocast carbon monoliths by iron, cobalt and nickel nanoparticles
    (Pergamon, 2018-08-01) Thambiliyagodage, C. J; Ulrich, S; Araujo, P. T; Bakker, M. G
    Hierarchically porous carbon monoliths containing metal (Fe, Co, Ni) nanoparticles were synthesized in a one-pot synthesis through a nanocasting technique using silica (SiO2) as the template. The macropore structure of SiO2 has been replicated in nanocast carbon and N2 adsorption analysis shows that the monoliths have high surface area, high mesopore volume, and that micropores are also present. The temperature effect on catalytic graphitization was studied by using x-ray diffraction (XRD), transmission electron microscope (TEM) and Raman spectroscopy. It is observed that iron was capable of producing turbostratic carbon at 500 °C, while turbostratic carbon was produced at temperatures of 700 °C when cobalt and nickel are present. Iron, cobalt, and nickel were found to be good graphitization catalysts with the order of catalytic activity being iron > cobalt > nickel. Raman spectroscopy experiments provide insight into the degree of ordering of the carbon of each sample and are in agreement with the results from the other techniques: with increasing pyrolysis temperature, with and without the presence of metals, ordering of amorphous carbon is confirmed. Detailed analysis of the Raman spectroscopic data showed clear differences between the metal catalyzed and non-catalyzed samples enabling the contributions from the two different mechanisms to be clearly distinguished.