Research Papers - Department of Civil Engineering

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Subject: search.filters.subject.Adsorption

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    PublicationOpen Access
    Greywater adsorption into soil during irrigation
    (Springer, 2022-02-23) Faisal Anwar, A. H. M; Rathnayake, U; Bowyer, W
    The reuse of greywater has signifcant potential to reduce the demand on potable water. The greywater produced from laundry is free from oil and grease and hence makes it attractive to reuse for irrigation. This study investigates the adsorption of surfactant-rich laundry greywater into the soil surfaces during irrigation. A series of miscible displacement column experiments was conducted under water-saturated condition using non-reactive (NaCl solution of concentration 0.650 g/L) and reactive tracers (greywater solution of concentration 0.26–0.442 g/L with same background electrolyte). Plasterer’s sand was used as the porous medium. Samples collected at the column outlet every two minutes were measured for pH, electrical conductivity and greywater concentrations. Hydraulic conductivity for each experiment was also determined using constant head method. Separate experiments were conducted to determine the surface tension of greywater solution (with same background electrolyte) and modelled using Gibbs adsorption isotherm. Surface tension of greywater reduces with increasing greywater concentration and becomes constant at greywater concentration of 0.440 g/L. The results revealed that pH is improved and electrical conductivity decreased indicating it may increase the soil salinity. The comparison of breakthrough curves of reactive and non-reactive tracers showed that the greywater adsorptions occur into the soil surfaces and it increased with greywater concentrations, which may make the soil water-repellent. This may be a concern if soil becomes water-repellent, increases hydraulic conductivity and enhances the risk of groundwater pollution. The concentration of greywater needs to be checked before irrigation and if needed, it should be diluted to avoid any risk of soil water-repellence.
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    PublicationOpen Access
    Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge
    (hindawi.com., 2022-03-22) Al-mahbashi, N; Kutty, S. R. M; Jagaba, A. H; Al-Nini, A; Ali, M; Saeed, A. A. H; Ghaleb, A. A. S; Rathnayake, U
    mong the water-polluting substances, heavy metals stand out due to their carcinogenic and toxic effects on the creatures and environment. This study aimed to scrutinize the effectiveness of sewage sludge-based activated carbon in the removal of copper and cadmium from aqueous solutions in column study. Detection of breakthrough curves and related parameters was conducted by varying bed depths (3, 6, and 9 cm). The solution with an initial metal concentration (IMC) of 100 ppm was pumped to the column at a flow rate of 2 mL/min. In the process of copper removal, the breakthrough points for depths 3 cm, 6 cm, and 9 cm were achieved at 10 min, 15 min, and 60 min, respectively, whereas breakthrough points of similar depths in cadmium removal process were achieved at 5 min, 10 min, and 30 min, respectively. Adsorption kinetics were analyzed using the Adams–Bohart, Yoon–Nelson, and Thomas kinetics models. The Adams–Bohart model described only the initial part of breakthrough curves. The Thomas model represented the adsorption process with coefficients of determination (R2) ranging between 0.90–0.95 for cadmium removal and 0.89–0.96 for copper removal, while the coefficients of determination of Yoon–Nelson ranged between 0.89–0.94 for cadmium and 0.95–0.97 for copper. Yoon–Nelson was fitted well with copper removal data, while removal of cadmium data was best described by the Thomas model. This study demonstrated that using sewage sludge-based activated carbon to remove heavy metals is an alternative, more cost-effective option to reach the objectives of sustainable development.